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Charles's law, Meaning (SPM Physics)

For a fixed mass of gas at constant pressure, the volume is directly proportional to its absolute temperature.

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EnglishCharles's law
Bahasa MelayuHukum Charles
中文查理定律

Definition

For a fixed mass of gas at constant pressure, the volume is directly proportional to its absolute temperature.

Heat

In exam terms

Charles's law states that for a fixed mass of gas at constant pressure, the volume is directly proportional to its absolute temperature. In symbols, V/T = constant, or V₁/T₁ = V₂/T₂, where V is volume in m³ and T is absolute temperature in kelvin (K).

When the gas is heated, its particles move faster and would strike the walls harder, so the gas expands to keep the pressure constant. The temperature must be in kelvin.

Worked line: V₁/T₁ = V₂/T₂ → (2.0 m³)/(300 K) = V₂/(450 K), so V₂ = 3.0 m³. Example of correct use: by Charles's law, warming a gas at constant pressure increases its volume in proportion to its absolute temperature.

Do not confuse it with…

Do not confuse Charles's law with Boyle's law or the pressure law. Charles's law keeps the pressure constant (volume against temperature), Boyle's law keeps the temperature constant (pressure against volume), and the pressure law keeps the volume constant (pressure against temperature).

In Paper 2 this is usually asked as state Charles's law, a V against T calculation, or a graph. The temperature must always be converted to kelvin using T/K = θ/°C + 273; using degrees Celsius directly is the most common error and gives the wrong ratio.

Source: DSKP KSSM Physics Form 4 and 5 (Versi English) (Bahagian Pembangunan Kurikulum (BPK), KPM)

Frequently asked questions

Why must temperature be in kelvin for Charles's law?
Because the volume is proportional to absolute temperature, which starts at absolute zero. Using degrees Celsius, which can be negative, breaks the proportion and gives a wrong answer.
What is kept constant for Charles's law?
The pressure of the gas and the mass (amount) of gas are both kept constant, so only the volume and temperature change.
What is the shape of the volume–temperature graph?
A straight line. When plotted against Celsius temperature it does not pass through the origin, but extended backwards it meets the axis at about −273 °C, absolute zero.

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